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1.
西藏林周县是我国大骨节病(KBD)患病较为严重的地区之一,本文将林周县作为研究区,通过使用地理探测器(GeoDetector)量化分析KBD患病率风险因子的影响,并使用环境化学方法验证空间分析结果。通过对10个潜在影响因子的分析以及对当地KBD患病村和非患病村的土壤-水-粮食-人这一生物地球化学循环的环境化学分析,结果表明:(1)林周县KBD由一组多重且交互作用的环境影响因子共同作用影响,其中最重要的控制因子是地层因子;(2)所有环境介质(土壤、水、谷物)及人体组织中的硒元素浓度在KBD患病区均低于非患病区;(3)当地居民对硒和铬的摄入严重不足,尤其是KBD患病村中居民硒元素平均日摄入量(ADD)大约仅为世界卫生组织(WHO)建议的成人基本摄入量下限的4%;(4)我们推测,当地居民患病主要是由于地层这一影响因子,这是由于通过生态系统的迁移转化导致当地人口严重硒缺乏,最终导致地方性生物地球化学硒缺乏。 相似文献
2.
3.
江西省德兴铜矿矿区重金属元素的环境效应 总被引:6,自引:0,他引:6
本文系统研究了德兴铜矿排石场和尾砂库的环境问题,以环境介质(水土植物)中重金属元素含量为研究对象,论述矿区重金属的环境效应。研究结果表明祝家村低品位矿石堆浸场淋滤产生的酸性废水是造成大坞河流域重金属污染的主要来源。大坞河上游水体中Cu元素含量高达14506μg/L,是国家Ⅲ级水标准的14倍之多,Zn元素含量高达2938μg/L,是国家Ⅲ级水标准的2.9倍,同时pH值在3~4范围内;到中下游水体中Cu元素含量减小到几千到几百μg/L,水质有所改善。大坞河沿岸上游和中游土壤重金属含量受河水影响,随着与河岸距离的增加而减小。同时水稻中Pb元素含量是国家粮食标准的2倍。推测4#尾砂库尾砂表层氧化带深度大于80cm;而1#尾砂库库内尾砂中氧化带估计在0~25cm处。推测两个尾砂库产酸能力小于酸中和能力,故坝底水中pH值在7左右,对周围水体影响较小。与4#尾砂库距离近的石墩头村稻田表层土壤中Cu、Mo元素含量较高,远离尾砂库土壤中重金属含量降低。同时4#尾砂库周围土壤中Cd、Pb、Cu元素的吸附态、碳酸盐态比例在20%左右,因而在酸性环境下较容易被植物吸收。1#尾砂库矿建村种植的小白菜中Pb元素含量超过国家蔬菜标准的4倍,Cu、Pb、Zn元素含量严重超过背景值。 相似文献
4.
E. García-Luque T. A. DelValls C. Casado-Martínez J. M. Forja A. Gmez-Parra 《Marine environmental research》2004,58(2-5):671
We describe the effect of heavy metals Zn, Cd, Pb and Cu on the induction of methallothioneins on the clam Scrobicularia plana along a salinity gradient simulated under laboratory conditions. The clams were exposed to constant heavy metal concentrations in a dynamic estuary simulator during a 15-day assay to investigate possible induction of metal-binding proteins in them. The concentration of heavy metals in water was analysed. Clams were analysed for methallothionein concentrations. The speciation of Zn, Cd, Pb and Cu along the salinity gradient was modelled. Zn showed the highest concentrations and its prevalent species was the free ion. Intersite differences have been observed in methallothionein concentration and related to the salinity gradient. It seems that synthesis of methallothioneins is the result of physiological forces acting in concert with the changes in the chemical speciation of metals, owing to the trace metals uptake is controlled by means of an interaction of physiology and physicochemistry. 相似文献
5.
The distribution of dissolved and participate concentrations of As, Cr and V was investigated in the mixing area of the Po river in five surveys over the period March 1992-March 1995. The data obtained indicate noticeable contamination of coastal waters of the northern Adriatic with Cr but not As or V. Total dissolved concentrations for As and V were comparable with oceanic levels but were higher by a factor of 4 for Cr. These results suggest either low anthropogenic inputs of As and V, from terrigenous and atmospheric sources, or efficient removal mechanisms. The investigated metals had low reactivity during freshwater-seawater mixing and the distribution of concentrations in the dissolved and solid phases suggests that the dilution process is the main factor controlling the transport of these metals to the sea in low-to-medium solid transport conditions. Further investigations are required to elucidate the behavior of these metals during high solid transport conditions. Significant changes in the speciation of As occurred during the transition between the two end-member matrices. In the coastal waters of the northern Adriatic, the arsenite fraction in winter, and the arsenite and dimethylarsinate fractions in summer increased with respect to riverine waters. Changes in the speciation of chromium were minor, but also showed a small increase in reduced species in marine waters. 相似文献
6.
The speciation of dissolved iodine and the distributions of the iodine species in the deep Chesapeake Bay underwent seasonal variations in response to changes in the prevailing redox condition. In the deep water, the ratios of iodate to iodide and iodate to inorganic iodine decreased progressively from the Winter through the Summer as the deep water became more poorly oxygenated before they rebounded in the Fall when the deep water became re-oxygenated again. The composition of the surface water followed the same trend. However, in this case, the higher biological activities in the Spring and the Summer could also have enhanced the biologically mediated reduction of iodate to iodide by phytoplankton and contributed to the lower ratios found during those seasons. Superimposed on this redox cycle was a cycle of input and removal of dissolved iodine probably as a result of the interactions between the water column and the underlying sediments. Iodine was added to the Bay during the Summer when the deep water was more reducing and removed from the Bay in the Fall when the deep water became re-oxygenated. A third cycle was the inter-conversion between inorganic iodine and ‘dissolved organic iodine’, or ‘‘DOI’’. The conversion of inorganic iodine to ‘DOI’ was more prevalent in the Spring. As a result of these biogeochemical reactions in the Bay, during exchanges between the Bay and the North Atlantic, iodate-rich and ‘DOI’-poor water was imported into the Bay while iodide- and ‘DOI’-rich water was exported to the Atlantic. The export of iodide from these geochemically reactive systems along the land margins contributes to the enrichment of iodide in the surface open oceans. 相似文献
7.
Size distribution of colloidal trace metals and organic carbon during a coastal bloom in the Baltic Sea 总被引:1,自引:0,他引:1
Johan Ingri Susanna Nordling Jenny Larsson Jenny Rnnegrd Nina Nilsson Ilia Rodushkin Ralf Dahlqvist Per Andersson
rjan Gustafsson 《Marine Chemistry》2004,91(1-4):117-130
The physico-chemical speciation of organic carbon and selected metals was measured during a coastal bloom in Ekhagen Bay, Baltic Sea, using ultrafiltration.One important objective with the study was to see if any depletion of trace metals could be measured in the directly bioavailable fraction (<1000 Da, the soluble low molecular weight fraction, LMW) during a plankton bloom. Filters with five different cut-offs were used (1 kD (1000 Da), 5 kD, 10 kD, 100 kD and 0.22 μm) in order to delineate the size distribution of colloidal organic carbon (COC) and trace metals.During the bloom in May, LMW Al, Co, Cu, Mn and Ni concentrations decreased although the colloidal and particulate concentrations were relatively high. Data show that desorption of colloidal and particulate bound trace metals to the LMW fraction was slower than the process depleting the LMW fraction.Estimates of the maximum active uptake of Cu, Ni and Mn by the phytoplankton, and the loss of non-bioactive Al from the LMW fraction, indicate that processes other than active uptake by phytoplankton must contribute to the observed depletion of trace metals in the LMW fraction. Hence, in order to estimate the bioavailable pool of trace metals for plankton during bloom conditions, these other processes must be understood and quantified.Transparent Exopolymeric Particles (TEP, reflecting sugar-rich phytoplankton exudates) increased around eight times during the plankton bloom. We hypothesize that the formation of TEP is a process that might be important for the transfer of trace metals from the LMW to the particulate fraction during the phytoplankton bloom, but the significance of TEP for this depletion in Baltic Sea surface water remains to be shown. 相似文献
8.
含硒紫球藻胞外多糖的制备及对体内外肿瘤细胞生长的影响 总被引:4,自引:0,他引:4
采用在培养液中添加亚硒酸来实现藻对无机硒的富集和转化,制备一种含硒的紫球藻(Porphyridiumsp.)胞外多糖(Se-PSP);通过DAN荧光法测硒含量及红外光谱,对硒是否结合在多糖上进行了初步探讨;用四唑盐比色法(MTT)研究了不同浓度含硒的紫球藻胞外多糖对3种体外肿瘤细胞生长的影响。通过建立荷瘤小鼠模型,研究了含硒多糖对腹水瘤S180的作用。结果表明含硒的胞外多糖含硒量约为0.015mg/g,40,80mg/LSe-PSP对3种肿瘤细胞SMMC7721、A549、A357均有一定程度的抑制作用,尤其是对SMMC7721抑制程度最为明显。荷瘤小鼠模型实验结果表明100mg/(kg.·d)Se-PSP可以延长荷瘤小鼠的生存时间,Se-PSP有可能成为一种抗肿瘤药物。 相似文献
9.
珠江口硒的形态分布特征 总被引:1,自引:0,他引:1
硒属于硫族元素,在化学和生物化学性质上,硒与硫、碲相似.它和砷一样也是一种类金属物质.硒广泛存在于自然界中,岩石、土壤、沉积物、水体、生物体以及大气环境都含有不同程度的硒.硒是生物必需的一种微量元素,一方面表现出重要的生物功能,另一方面在较高浓度下也表现出毒性,摄入过多可导致动物和人硒中毒[1].在陆源硒向海洋的输送中河流占重要贡献,河流可能是溶解硒输入海洋的主要来源[2,3].河口区是陆地径流与海水相互混合的地带,其中发生的反应直接影响元素的入海通量,因此研究河口化学元素的行为对估计河流向海洋的输入及建立全球生物地球化学循环模型有十分重要的意义. 相似文献
10.
Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas 总被引:3,自引:0,他引:3
The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (Ls), ranging from 19 to 93 pM with an average conditional stability constant (KHgLs) of 1028, and a weak class (Lw) ranging from 1.4 to 9.8 nM with an average KHgLs of 1023. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgClx, Hg(OH)x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters. 相似文献